Webas effective anion receptors in water (i) when containing two coordinatively unsaturated metal ions, and (ii) when protonated at the secondary amine groups. Representative examples of the two approaches will be discussed in the following sections. Some cryptand-related reviews have been published recently.3–5 Origin and development of ... WebSep 17, 2010 · The design of supramolecular hosts for anions began with simple diaza bicycles, named katapinands, and has evolved over the last 40 years to a number of …
Preface: supramolecular chemistry of anionic species …
WebAug 20, 2024 · Cryptand 1 was obtained by an acetylenic coupling reaction and, despite our expectation to have a shape-persistent compound with a large internal cavity, the single crystal X-ray diffraction molecular structure of cryptand 1 showed the completely collapsed cavity behavior of the cryptand [ 17 ]. WebAug 1, 2024 · Both the inner voids (cavity and cleft) are accessible to various guests such as metal ions, anions and, neutral molecules. The pyrrole ring offers hydrogen bond donor NH groups and its... brian inge beacon\u0027s bible church
Bistren cryptands and cryptates: versatile receptors for …
WebThe novel cryptand in/out-3, containing two tripyrrolemethane units bridged by three 1,3- diisopropylidenbenzene arms, was readily synthesized by a convergent three-step … WebPerhaps unsurprisingly, the earliest anion receptor, reported by Park and Simmons in 1968, was a cryptand-like macrobicyclic host that encapsulated halides between the ammonium groups located at the poles of its cavity. 9 More recently, mechanically-interlocked molecules, such as catenanes and rotaxanes, have emerged as promising … WebThe impact of the solvent environment on the stabilization of the complexes formed by fluorine (T-F) and cyanide (T-CN) substituted tweezers with halide anions has been investigated theoretically. The study was carried out using computational methodologies based on density functional theory (DFT) and symmetry adapted perturbation theory … brian ines